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class="solid-rw"> <table width="742" border="0" cellspacing="0" cellpadding="0"> <tr> <td height="32" class="center_bg"> <table width="100%" border="0" cellspacing="0" cellpadding="0"> <tr> <td width="56" align="center"><img src=/homes/images/zhuanzai.gif border=0></td> <td width="567" align="left"><span class="title">聚æ°}酯èÊY泡常见问题和解决æ–ÒŽ¡ˆ</span>   <font color=#999999>(2019-8-27 8:52:33)</font></td> <td width="119" style="font-family:'宋体';"><img src="/space/images/zhuanlan.jpg" align="absmiddle"> <a href="/space/blog_post.asp" class="link3">发表博文</a></td> </tr> </table> </td> </tr> <tr><td height="" valign="top" align="center"> <table width="98%" border="0" cellspacing="0" cellpadding="0" align="left"> <tr> <td height="8"></td> </tr> <tr><td align="center" height="100" valign="top"> <table width="99%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr><td class=red_2 align=left><script src='/homes/Blog_tuijian.asp?Id=75371'></script></td></tr> <tr> <td align="left"> <table width="98%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr> <td class="style_14_666666"> <div class="f401" id="f401"><p><span style="font-size:14px;">  <b><span style="font-size:16px;color:#337fe5;">1、闭孔率é«?/span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (1)、聚醚多元醇:环氧乙烷比例高、活性高、多发生在更换不同活性的聚醚多元é†?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (2)、工艺配方:辛酸亚锡用量å¤?异氰酔R…¯‹zÀL€§é«˜,交联度大,交联速度å¿?˜q‡å¤šçš„胺和物理发泡剂; 造成泡沫内压ä½?泡沫å¼ÒŽ€§å¤§æ—¶ä¸èƒ½å¼€å­?TDI指数˜q‡å¤§æ—¶ä¹Ÿä¼šå¯¼è‡´é—­å­”率高ã€?/span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">2、收¾~?凝胶速度大于发æˆö速度)</span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (1)、闭孔率é«?冷却时收¾~?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (2)、工艺条ä»?气温ä½?料温ä½?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (3)、工艺配æ–?¼‹…æÑa˜q‡é‡,物理发æˆö剂过é‡?TDI指数˜q‡ä½Ž.</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">3、内è£?/span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (1)、工艺条ä»?气温ä½?反应中心温度é«?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (2)、工艺配æ–?TDI指数ä½?锡多,早期发æˆö强度é«?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (3)、硅æ²ÒŽ´»æ€§é«˜,用量ž®?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">4、顶è£?发气凝胶速度不åã^è¡?</span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (1)、工艺条ä»?气温ä½?料温ä½?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (2)、工艺配æ–?催化剂用量不­‘?胺用量少,¼‹…æÑa质量不好.</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">5、底角裂(胺用量过å¤?发æˆö速度太快)</span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  表面大孔:物理发æˆö剂量˜q‡å¤§,¼‹…æÑa和催化剂质量å·?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">6、æˆö沫低温性能å·?/span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  聚醚多元醇内在质量差,在同¾ŸŸåŸºå€?官能度低,不饱和度å¤?同样锡用量时,TDI指数ä½?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">7、通气性差</span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (1)、气候条ä»?气温ä½?/span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (2)、原æ–?聚醚多元醇高,¼‹…æÑa‹zÀL€§é«˜;</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (3)、工艺配æ–?锡多,或锡用量相同时水与胺含量ž®?TDI指数é«?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">8、反å¼ÒŽ€§å·®</span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (1)、原æ–?聚醚多元醇活性高,相对分子质量ž®?¼‹…æÑa‹zÀL€§é«˜;</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (2)、工艺配æ–?¼‹…æÑa量大,锡量å¤?在相同锡用量时水å¤?TDI指数é«?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">9、拉伸强度差</span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (1)、原æ–?低分子聚醚多元醇˜q‡å¤š,同羟基值官能度ä½?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (2)、工艺配æ–?锡少凝胶反应不好,在相同锡用量æ—?TDI指数é«?水少交联度低ã€?/span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">10、发泡时冒烟</span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  ˜q‡é‡èƒÞZ¿ƒä½¿æ°´ä¸ŽTDI反应攑ևºå¤§é‡çƒ­é‡,低沸点物质蒸发而冒çƒ?若不是焦å¿?则烟气多数由TDI、低沸点物质以及聚醚多元醇中的单体环çƒïLƒƒ¾l„成ã€?/span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;"> <b><span style="color:#337fe5;font-size:16px;"> 11、æˆö沫带白筋</span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  发æˆö和凝胶反应速度å¿?在连¾l­å‘泡中传递速度æ…?局部挤压而生成致密层,产生白筋现象.应及时提高传递速度,或降低料æ¸?降低催化剂用</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">12、æˆö沫酥è„?/span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  配方中水多,生成¾~©äºŒè„²å¤šæœ‰æœªæº¶è§£äºŽç¡…æ²?锡催化剂用差åQŒäº¤è”反应不充分,ž®ç›¸å¯¹åˆ†å­è´¨é‡èšé†šå¤šå…ƒé†‡å«é‡ååº”温度˜q‡é«˜,醚键断裂降低了æˆö沫强åº?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">13、æˆö沫密度低于设定å€?/span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  发æˆö指数因计量不准而过å¤?气温é«?气压ä½?</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  <b><span style="color:#337fe5;font-size:16px;">14、æˆö沫有底皮、边皮、底步空åŒ?/span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  锡多胺少,发æˆö速度æ…?凝胶速度å¿?在连¾l­å‘泡中带温˜q‡ä½Ž.</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;"> <b><span style="color:#337fe5;font-size:16px;"> 15、äŽ×长率å¤?/span></b></span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (1)、原料:聚醚多元醇活性高,官能度小;</span></p><span style="font-size:14px;"> </span><p><span style="font-size:14px;">  (2)、工艺配方:TDI指数低交联不­‘?锡多,¼‹…æÑa多ã€?/span></p></div> </td></tr></table> </td> </tr> <tr><td height="15" align="center"><SCRIPT 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